See Angelina Jolie and Brad Pitt's best red carpet looks

In 2005, they promoted "Mr. & Mrs. Smith" together and stood at an awkward distance. Jolie opted for a silky, patterned slip dress. Pitt chose all-black everything in a leather suit jacket.

For the 2006 New York City premiere of "The Good Shepard," Jolie went for a night-sky-inspired sparkly shift dress. Pitt, a sharply tailored suit.

At the 64th Annual Golden Globe Awards, the actress went for a long, Grecian gown in a muted tone.

Jolie chose a little black cocktail dress (and little black peep-toe pumps) at the Cannes premiere of "A Mighty Heart" in 2007. Pitt was ever-so playful in a dashing bow tie.

Yellow is the color of sunshine, buttercups, happiness ... and Jolie's dress for the Cannes festival premiere of "Ocean's Thirteen."

On her: A long, scoop-neck gown with a delicate black lace overlay. On him: A white dinner jacket of which any gentleman's club would approve. The event: The "Assassination of Jesse James" premiere at the Venice Film Festival.

Only these two could make business casual look so red carpet ready at the 2007 premiere of "The Assassination of Jesse James" in Deauville, France.

At the New York City premiere of "Changeling" in 2008, Jolie went short and strapless. And Pitt, well, he wore a scarf (expect more of those to come).

What do you get when you combine a long, patterned maxi dress, a three-piece tweed suit and the biggest smiles ever? What seemed to be true love at the 2008 Santa Barbara International Film Festival where Jolie was honored for "A Mighty Heart."

At the 2008 Spirit Awards, she kept things simple in all black with flirty flutter sleeves. He opted for tweed pants, a suede blazer and cowboy boots. You do you, Brad.

Jolie wore a mauve goddess dress when she was pregnant with the twins at the Cannes premiere of "Changeling" in May of 2008.

Pregnant with Knox and Vivienne at the 2008 Cannes premiere of "Kung Fu Panda," Jolie wore a moss-hued Max Azria creation. 

A 2009 premiere of "Invictus" in Beverly Hills called for a stock cap for dad, a straw hat for Maddox and a metallic, kimono-style robe for mom. Who says the Jolie-Pitts aren't like every other family?

Jolie is dripping in peach silk at the 2009 Cannes premiere of "Inglourious Basterds."

In 2009, Pitt returned to his favorite accessory: the tried-and-true scarf. Jolie went with a structural cocktail dress lined with canary-colored satin.

She was cool blue in floor-length silk at the 2009 Screen Actors Guild Awards in Los Angeles. Look closely: His pocket square matches her gown.

The duo chose a matching look for the Paris premiere of "The Curious Case of Benjamin Button" in 2009.

They showed off their yin-and-yang sides at the Berlin premiere of "The Curious Case of Benjamin Button." A white pantsuit for her, a black tux (with a scarf, of course) for him.

At the 2009 Golden Globes, Jolie's silver gown was so shimmery, Pitt needed to wear his shades.

At the 2010 premiere of "Salt," she wore an itsy-bitsy, teeny-weeny, black-sequined dress. He opted to leave his blue shirt open and loose.

Correct us if we're wrong here, but it looks like he's wearing leather sweatpants and she's wearing velvet ones, no? Only the best for the 2010 Paris premiere of "Megamind."

The only way a nearly see-through sparkly spaghetti strap tank top could ever work on the red carpet is if it's tucked in to a lush, velvet ballroom skirt. Well done! Pitt, in all black, is the perfect neutral arm candy at "The Tourist" premiere.

Two black suits for two big stars at the Rome premiere of "The Tourist" in 2010. His is accessorized with a scarf and hat; hers, classic red lipstick. 

Oh, you didn't know they make floor-length wrap dresses in ivory cashmere? We didn't either, but Jolie wore one to the New York City premiere of "The Tourist" in 2010. 

One gets the sense that Jolie might not envy anyone. But her head-to-toe emerald sequined number at the 2011 Golden Globes definitely has us seeing green.

The duo hit the "Moneyball" premiere at the 2011 Toronto International Film Festival in all-black everything. (Sensing a theme here?) Her high-shine gold clutch added a touch of bling.

What to do if you love wearing black, but can't always wear it for fear of becoming too predictable? Try navy, like Pitt and Jolie at the 2011 premiere of "In the Land of Blood and Honey."

A studious-looking Pitt had a hot date in a slinky red slip dress and matching lips at the Tokyo premiere of "Moneyball" in 2011.

Jolie's leg had its first major red carpet moment peeking out of a slit skirt at the 2011 "Kung Fu Panda 2" premiere in Hollywood. As for Pitt's camel sweatsuit? We're not mad at it.

The couple went to "The Tree of Life" premiere at Cannes with Pitt in tinted sunglasses and Jolie wrapped in yards of milk chocolate-hued satin.

Jolie went with a draped, '70s-inspired halter gown for the 2012 Screen Actors Guild Awards in Los Angeles.

A meme was born at the 2012 Oscars when Angelina Jolie's leg took center stage, poking out proudly from her high-cut gown.

Here, the couple offer a study in contrasts. On her: A gauzy white blouse tucked into a sharp leather skirt. On him: Black and navy are strangely wonderful bedfellows.

Traditionally, white roses represent new beginnings. In February 2012, the couple attended the Paris premiere of "In the Land of Blood and Honey." In April of that same year, they announced that they were engaged.

Jolie wore one of her most famous gowns ever in 2012 — a nude silk lined gown with crimson — to the 2012 Golden Globe Awards. Pitt walked with a dapper cane.  

The 2013 Berlin premiere of "World War Z" called for a white peplum dress and casual, head-to-toe black ensemble.

For the London premiere of "World War Z," black was definitely back. Even Pitt's T-shirt was in on the action.

At the "Maleficent premiere in Hollywood, it looked like Jolie's gown was fashioned from the world's prettiest heavy-duty trash bags. (Sources close to the star tell us that was not the case.)

It was Pitt's double-breasted, navy-accented blazer that made the biggest fashion statement of the two at the premiere of "The Normal Heart" in New York City.

Twinkle, twinkle gorgeous dress, would you like to attend the 2014 Oscars with the world's most famous couple?

It was matchy-matchy menswear at the EE British Academy Film Awards in London in 2014.

Jolie looked positively bridal in a sparkly column gown for the 2015 premiere of "By the Sea."

Not every event is cause for dressing up. Here, the couple go casual-cool for the 15th Annual AFI Awards in 2015.