The "Once Upon a Time in Hollywood" star was asked by "Entertainment Tonight" ahead of Sunday night's 77th Annual Golden Globe Awards if he would welcome bumping into the "Morning Show" star at the ceremony.
"I'll run into Jen,'' he said. "She's a good friend."
Pitt, 56, joked that it would be the "second-most important reunion of her year," referring to her "Friends" reunion with the cast of the iconic show on Instagram in October and the never-ending rumors that they will reunite for a reboot of the show.
The former couple, who were married from 2000 to 2005, also shared a moment at the Globes during Pitt's acceptance speech after winning Best Supporting Actor in a Motion Picture for "Once Upon a Time in Hollywood."
The NBC cameras panned to Aniston, 50, multiple times during his speech, showing her give a little smirk as Pitt said, "I wanted to bring my mom, but I couldn’t because anyone I stand next to they say I’m dating. It’d just be awkward."
The internet couldn't help but be grateful for that little bit of interaction between the former couple.
The moment with both of them on screen Sunday night brought back memories of the days of them attending the Golden Globes as a couple back in 2002.
Since splitting up, the two have both been through other marriages, as Aniston divorced Justin Theroux in 2018, while Pitt split from Angelina Jolie in 2016.